Blaziken vs Unown G (a situation that i cannot find on this forum)

[Dsurion]

I have not been able to search out this situation already on this ruling forum.

My opponent has an active NidoKing. Also a benched Nidoqueen with Unown G attached.

During my turn I use luring flame against the nidoking, with nidoqueen as the intended for the new active.

what would happen in this case?

[PokePop]

Nothing would happen.
No switch.
And, since there is no "new Defending Pokemon", no Burn condition either.