You see 10 energy cards together. Your mindset is that you'd rather declump because it would take a ton of shuffling to break apart that pattern. So instead, you declump. Now, you don't feel obligated to complete that lengthy shuffle.
But wait a minute, why would you have to shuffle less after declumping? Does it actually take less shuffles to randomize a deck because you've artificially moved cards around? No, once you've seen a deck, it is no longer random, regardless of the order of the cards. Whatever amount of shuffling was necessary to randomize the deck when there were 10 energy cards next to each other is still required even if you moved those energy cards around.
As stated previously, seeing the order of cards in the deck does not make it not random. However, the purpose of randomization is not randomization for its own sake. Decks are randomized to prevent the player from knowing the order of cards and that is why you must shuffle after every search.
"Declumping" and stacking a deck are in reality the same thing, but different degrees. Both are attempting to do the same thing: to create an artificial order of cards that is more likely to produce good draws. There's a reason "declumping" isn't an actual term in card games outside of these forums. If we went into a poker forum, or perhaps another respectable TCG forum, it would just be called "stacking." (I can only imagine the reaction to watching a poker dealer break apart the aces in a deck before performing a light shuffle. "Imagine how unrandom it would be if the flop had three aces," he explains.)
Now, there is no real definition for the word "clump" as used here, but I think there are two different types of clumps. First, there are clumps of same-type cards (such as a group of 4 Fire Energy). Second, there are clumps of complimentary cards (such as a complete evolution line). Given a less than perfect randomization, de-clumping type one may improve your hand while de-clumping type two may degrade it.
Here's the trouble: there will not always be a perfectly randomized deck. I have been playing TCGs for 18 years and I still can't perform a riffle shuffle. I'm sure I'm not the only one who fails at that skill. Some players simply won't do it because of risk to card condition. Other forms of shuffling may be less randomizing (though I'm not completely convinced) and you can't check for randomization without looking at the cards. Obviously that would defeat the purpose.
Pile shuffling de-clumps your deck without telling you what order the cards are in (unless you've stacked the deck as mentioned earlier). This way, even if you do not perform a perfect shuffle you won't know what cards are likely to be next to others and that preserves the spirit of the rule.
RM