Considering the "Round" attack in the videogames wasn't created until B/W, I'd doubt there would be any pokemon in the card game that would have that attack before B/W.
While it isn't the case for Round, stuff like this has happened before. From the classic four sets alone we had:
Base Blastoise - Rain Dance (move introduced in Gen II)
Base Poliwrath/Rocket Dark Vaporeon - Whirlpool (II)
Base Porygon - Conversion 2 (II)
Base Diglett - Mud Slap (II)
Base Gastly - Destiny Bond (II)
Base Magikarp/Fossil Kingler - Flail (II)
Jungle Pidgeot - Hurricane (V)
Jungle Pikachu - Spark (II)
Fossil Haunter/Rocket Drowzee - Nightmare (II)
Fossil Arbok - Poison Fang (III)
Fossil Golduck/Slowbro, Rocket Abra - Psyshock (III)
Fossil Golem - Avalanche (IV)
Rocket Machamp - Fling (IV)